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COMPOSITE MATERIALS
1
The world of materials
PE, PP
PA (Nylon)
Polymers,
elastomers
Butyl rubber
Neoprene
Polymer foams
Metal foams
Foams
Ceramic foams
Glass foams
Woods
Natural
materials
Natural fibres:
Hemp, Flax,
Cotton
GFRP
CFRP
Composites
KFRP
Plywood
Alumina
Si-Carbide
Ceramics,
glasses
Soda-glass
Steels
Cast irons
Al-alloys
Metals
Cu-alloys
Ni-alloys
Ti-alloys
2
Definition
• A broad definition of composite is: Two or more
chemically distinct materials which when combined
have improved properties over the individual
materials.
• The constituents retain their identities in the
composite; that is, they do not dissolve or otherwise
merge completely into each other, although they act
in concert.
3
Advantages of Composites
• Light in weight
• Strength-to-weight and Stiffness-to-weight are greater than
steel or aluminum
• Fatigue properties are better than common engineering
metals
• Composites cannot corrode like steel
• Possible to achieve combinations of properties not
attainable with metals, ceramics, or polymers alone
4
Components in a Composite Material
• Nearly all composite materials consist of two
phases:
1. Primary phase - forms the matrix within which the
secondary phase is imbedded
1. Secondary phase - imbedded phase sometimes referred
to as a reinforcing agent, because it usually serves to
strengthen the composite
• The reinforcing phase may be in the form of fibers, particles, or
various other geometries
5
Functions of the Matrix Material
(Primary Phase)
• Provides the bulk form of the part or product made
of the composite material
• Holds the imbedded phase in place, usually enclosing
and often concealing it
• When a load is applied, the matrix shares the load
with the secondary phase, in some cases deforming
so that the stress is essentially born by the
reinforcing agent 6
The Reinforcing Phase
(Secondary Phase)
• Function is to reinforce the primary phase
• Imbedded phase is most commonly one of the
following shapes:
– Fibers
– Particles
– Flakes
7
Factors in Creating Composites
Matrix material
Reinforcement material
– Concentration
– Size
– Shape
– Distribution
– Orientation
8
9
Classification
Large-
particle
Dispersion-
strengthened
Particle-reinforced
Continuous
(aligned)
Aligned Randomly
oriented
Discontinuous
(short)
Fiber-reinforced
Laminates Sandwich
panels
Structural
Composites
Based on type of reinforcement
10
Large particle reinforced
composites
• Particle size is 1-50µm
• Concentration usually ranges from 15-40% by volume
• The particulate phase is harder and stiffer than the matrix.
• Particles provide strength to the composite by restraining the
movement of the matrix
• Cermets-tungsten carbide or titanium carbide
• Vulcanized rubber- carbon black in rubber
• Concrete- sand and gravel particulate in a surry of cement
matrix.
11
Dispersion strengthened
composites
• Uniformly dispersed fine, hard and inert particles of size less
than 0.1µm are used as reinforcement
• The volume fraction is between 5-15%
• These particles are stronger than the pure metal matrix and can
be metallic, inter-metallic or nonmetallic.
• Matrix is the load bearing phase
• Eg. SAP, TD-Nickel, Cu-Al2O3, Cu-Zn-Al2O3
12
Particules as the reinforcement
(Particulate composites)
13
Fillers as the reinforcement (Filler
composites)
14
Fibre Reinforced Composites(FRP)
1. Continuous fibre reinforced composites
2. Discontinuous fibre reinforced composites
15
Random fiber (short fiber) reinforced
composites
16
Continuous fiber (long fiber) reinforced
composites
17
Typical Reinforcement Geometries for
Composites
18
OTHER COMPOSITE STRUCTURES
Laminar composite structure :-
Two or more layers bonded
together in an integral piece
Sandwich structure:- foam &
honey cores
Consists of a thick core of low
density foam bonded on both
faces to thin sheets of a
different material
19
Classification based on Matrices
Composite
materials
Matrices
Polymer Matrix
Composites (PMC)
Metal Matrix
Composites MMC)
Ceramic Matrix
Composites (CMC)
Thermoset Thermoplastic Rubber
20
Role of matrix phase
• Primary function of the matrix phase in a composite is to hold
and bind the reinforcing phase in position within it
• Act as a medium through which the external load is
transmitted and distributed to the reinforcing phase.
• It separates fibres from each other
• Protects the individual fibres from surface damage due to
abrasion and oxidation
• Improves fracture toughness of the composite
• Withstand heat or cold, conduct or resist electricity, control
chemical attack
21
Polymer Matrix Composites
In PMCs polymer is the primary phase in which a secondary
phase is imbedded as fibers, particles, or flakes
• Commercially, PMCs are more important than MMCs or CMCs
• Low density, high specific strength, high specific stiffness, ease
of fabrication.
• Examples: Rubber reinforced with carbon black and
fiber-reinforced pastic (FRPs)
22
MATRIX & REINFORCEMENT
MATRIX
• Thermosetting polymers are the most common matrix materials
– Principal TS polymers are:
• Phenolics – used with particulate reinforcing phases
• Polyesters and epoxies - most closely associated with FRPs
• Nearly all rubbers are reinforced with carbon black
REINFORCEMENT
• Possible geometries - (a) fibers, (b) particles & (c) flakes
• Particles and flakes are used in many plastic molding compounds
• Of most engineering interest is the use of fibers as the reinforcing phase in
FRPs
23
Glass fibre reinforced polymer
composites
• Contains glass fibre as reinforcing phase in a
polymer matrix
• Glass fiber
• Continuous or discontinuous
• Dia b/w 3-20μm
• Lim: not very stiff and rigid
• Automobile and marine bodies, storage
containers, plastic pipes, industrial flooring
24
Carbon fibre reinforced polymer
composites
• Contains carbon fibre as reinforcing phase in a
polymer matrix
• Advantages
• High specific strength and specific modulus
• Higher strength at elevated temperatures
• Not affected by moisture or acids
• Applications
• Aerospace application
• Sports and recreational equipments
• Pressure vessels
25
Aramid fibre reinforced polymer
composites
• Aramid-polyamide-kevlar or nomex
• Advantages
• High toughness and impact resistance
• Resistance to creep and fatigue failure
• Applications
• Bullet proof vests and armor
• Sports goods, missile cases
• Pressure vessels, clutch linings and gaskets
26
Metal matrix composites
• Metals with low density and low temperature toughness are
preferred as matrix metal.
• Aluminium, titanium, magnesium and their alloys
• Advantages
• Higher operating temperatures
• Non flammability and creep resistance
• Greater resistance to degradation by organic fluids.
• Applications
• Aerospace application
• Gas turbine blades
• Electrical contacts
27
Ceramic Matrix Composites
• Primary objective for developing CMCs was to enhance the
toughness while retaining the high temperature properties.
• High melting points and good resistance to oxidation
• But low tensile strength, impact resistant and shock resistance
• eg. Small particles of partially stabilized Zirconia are dispersed
within a matrix material Al2O3
28
Hybrid composites
• Obtained by using different kinds of fibers in a
single
29
Applications
1. Aircraft and aerospace applications
2. Automotive applications
3. Marine applications
4. Sporting industries
5. Biomaterials
6. Industrial applications
30
Lower Drag Brace for the F16
Lower Drag Brace of F16:
Landing gear
Titanium Matrix Composite
Monofilament SiC fibres in a Ti-matrix.
31
Lightweight Composite Core for Power Lines
Lightweight Aluminum Conductor Composite Core (ACCC)
o Composite Technology Corporation (CTC)
o Twice the amount of electric power as
conventional power lines.
32
Brake rotors for high speed train
Brake rotors for high speed train
• particulate reinforced Aluminium alloy (AlSi7Mg+SiC
particulates)
• Weight of cast iron rotor is 120 kg/piece while MMC it is 76
kg/piece
33
Cylinder liner
Boxter engine block
 Cylinder liner AlSi9Cu3 alloy with 25% Si.
 Squeeze casting infiltration
34
F-16 Fuel Access Door Covers
• High specific strength and
stiffness good bearing strength
• Al Composites
• 6092/SiC/17.5p
• Wrought P/M material
• Elimination of the skin cracking
problem
35
F-16 Ventral Fins
• High specific stiffness and
strength
• Al-matrix composites
• Rolled P/M
• 6092/SiC/17.5p
• Decreased deflections
provide an increase in fin
life
36
Recreational products
Skating shoe
Base ball shafts
Horse shoes
Bicycle Frames
37
Space Shuttle
• Mid fuselage frames of Space Shuttle was made of MMCs
38
Common MMCs and Applications
39
Metal Matrix Automotive Brake
Caliper
Aluminum-matrix composite brake
caliper using nanocrystallyne
alumina fiber reinforcement.
40
Application of advanced composite materials in Boeing 757-200 commercial aircraft.
Source: Courtesy of Boeing Commercial Airplane Company.
41
Boeing C-17 Globemaster III
(large military transport aircraft)
42
Cross-section of a composite sailboard.
Source: K. Easterline, Tomorrow’s Materials (2nd ed.), p. 133. Institute of Metals, 1990.
43
Helicopter rotor blade
44
Wing Panel
Aerospace parts
Automotive structure
45
46
47
Disadvantages and Limitations of
Composite Materials
• Properties of many important composites are anisotropic - the
properties differ depending on the direction in which they are
measured – this may be an advantage or a disadvantage
• Many of the polymer-based composites are subject to attack
by chemicals or solvents, just as the polymers themselves are
susceptible to attack
• Composite materials are generally expensive
• Manufacturing methods for shaping composite materials are
often slow and costly
48

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Composite materials

  • 2. The world of materials PE, PP PA (Nylon) Polymers, elastomers Butyl rubber Neoprene Polymer foams Metal foams Foams Ceramic foams Glass foams Woods Natural materials Natural fibres: Hemp, Flax, Cotton GFRP CFRP Composites KFRP Plywood Alumina Si-Carbide Ceramics, glasses Soda-glass Steels Cast irons Al-alloys Metals Cu-alloys Ni-alloys Ti-alloys 2
  • 3. Definition • A broad definition of composite is: Two or more chemically distinct materials which when combined have improved properties over the individual materials. • The constituents retain their identities in the composite; that is, they do not dissolve or otherwise merge completely into each other, although they act in concert. 3
  • 4. Advantages of Composites • Light in weight • Strength-to-weight and Stiffness-to-weight are greater than steel or aluminum • Fatigue properties are better than common engineering metals • Composites cannot corrode like steel • Possible to achieve combinations of properties not attainable with metals, ceramics, or polymers alone 4
  • 5. Components in a Composite Material • Nearly all composite materials consist of two phases: 1. Primary phase - forms the matrix within which the secondary phase is imbedded 1. Secondary phase - imbedded phase sometimes referred to as a reinforcing agent, because it usually serves to strengthen the composite • The reinforcing phase may be in the form of fibers, particles, or various other geometries 5
  • 6. Functions of the Matrix Material (Primary Phase) • Provides the bulk form of the part or product made of the composite material • Holds the imbedded phase in place, usually enclosing and often concealing it • When a load is applied, the matrix shares the load with the secondary phase, in some cases deforming so that the stress is essentially born by the reinforcing agent 6
  • 7. The Reinforcing Phase (Secondary Phase) • Function is to reinforce the primary phase • Imbedded phase is most commonly one of the following shapes: – Fibers – Particles – Flakes 7
  • 8. Factors in Creating Composites Matrix material Reinforcement material – Concentration – Size – Shape – Distribution – Orientation 8
  • 9. 9
  • 11. Large particle reinforced composites • Particle size is 1-50µm • Concentration usually ranges from 15-40% by volume • The particulate phase is harder and stiffer than the matrix. • Particles provide strength to the composite by restraining the movement of the matrix • Cermets-tungsten carbide or titanium carbide • Vulcanized rubber- carbon black in rubber • Concrete- sand and gravel particulate in a surry of cement matrix. 11
  • 12. Dispersion strengthened composites • Uniformly dispersed fine, hard and inert particles of size less than 0.1µm are used as reinforcement • The volume fraction is between 5-15% • These particles are stronger than the pure metal matrix and can be metallic, inter-metallic or nonmetallic. • Matrix is the load bearing phase • Eg. SAP, TD-Nickel, Cu-Al2O3, Cu-Zn-Al2O3 12
  • 13. Particules as the reinforcement (Particulate composites) 13
  • 14. Fillers as the reinforcement (Filler composites) 14
  • 15. Fibre Reinforced Composites(FRP) 1. Continuous fibre reinforced composites 2. Discontinuous fibre reinforced composites 15
  • 16. Random fiber (short fiber) reinforced composites 16
  • 17. Continuous fiber (long fiber) reinforced composites 17
  • 18. Typical Reinforcement Geometries for Composites 18
  • 19. OTHER COMPOSITE STRUCTURES Laminar composite structure :- Two or more layers bonded together in an integral piece Sandwich structure:- foam & honey cores Consists of a thick core of low density foam bonded on both faces to thin sheets of a different material 19
  • 20. Classification based on Matrices Composite materials Matrices Polymer Matrix Composites (PMC) Metal Matrix Composites MMC) Ceramic Matrix Composites (CMC) Thermoset Thermoplastic Rubber 20
  • 21. Role of matrix phase • Primary function of the matrix phase in a composite is to hold and bind the reinforcing phase in position within it • Act as a medium through which the external load is transmitted and distributed to the reinforcing phase. • It separates fibres from each other • Protects the individual fibres from surface damage due to abrasion and oxidation • Improves fracture toughness of the composite • Withstand heat or cold, conduct or resist electricity, control chemical attack 21
  • 22. Polymer Matrix Composites In PMCs polymer is the primary phase in which a secondary phase is imbedded as fibers, particles, or flakes • Commercially, PMCs are more important than MMCs or CMCs • Low density, high specific strength, high specific stiffness, ease of fabrication. • Examples: Rubber reinforced with carbon black and fiber-reinforced pastic (FRPs) 22
  • 23. MATRIX & REINFORCEMENT MATRIX • Thermosetting polymers are the most common matrix materials – Principal TS polymers are: • Phenolics – used with particulate reinforcing phases • Polyesters and epoxies - most closely associated with FRPs • Nearly all rubbers are reinforced with carbon black REINFORCEMENT • Possible geometries - (a) fibers, (b) particles & (c) flakes • Particles and flakes are used in many plastic molding compounds • Of most engineering interest is the use of fibers as the reinforcing phase in FRPs 23
  • 24. Glass fibre reinforced polymer composites • Contains glass fibre as reinforcing phase in a polymer matrix • Glass fiber • Continuous or discontinuous • Dia b/w 3-20μm • Lim: not very stiff and rigid • Automobile and marine bodies, storage containers, plastic pipes, industrial flooring 24
  • 25. Carbon fibre reinforced polymer composites • Contains carbon fibre as reinforcing phase in a polymer matrix • Advantages • High specific strength and specific modulus • Higher strength at elevated temperatures • Not affected by moisture or acids • Applications • Aerospace application • Sports and recreational equipments • Pressure vessels 25
  • 26. Aramid fibre reinforced polymer composites • Aramid-polyamide-kevlar or nomex • Advantages • High toughness and impact resistance • Resistance to creep and fatigue failure • Applications • Bullet proof vests and armor • Sports goods, missile cases • Pressure vessels, clutch linings and gaskets 26
  • 27. Metal matrix composites • Metals with low density and low temperature toughness are preferred as matrix metal. • Aluminium, titanium, magnesium and their alloys • Advantages • Higher operating temperatures • Non flammability and creep resistance • Greater resistance to degradation by organic fluids. • Applications • Aerospace application • Gas turbine blades • Electrical contacts 27
  • 28. Ceramic Matrix Composites • Primary objective for developing CMCs was to enhance the toughness while retaining the high temperature properties. • High melting points and good resistance to oxidation • But low tensile strength, impact resistant and shock resistance • eg. Small particles of partially stabilized Zirconia are dispersed within a matrix material Al2O3 28
  • 29. Hybrid composites • Obtained by using different kinds of fibers in a single 29
  • 30. Applications 1. Aircraft and aerospace applications 2. Automotive applications 3. Marine applications 4. Sporting industries 5. Biomaterials 6. Industrial applications 30
  • 31. Lower Drag Brace for the F16 Lower Drag Brace of F16: Landing gear Titanium Matrix Composite Monofilament SiC fibres in a Ti-matrix. 31
  • 32. Lightweight Composite Core for Power Lines Lightweight Aluminum Conductor Composite Core (ACCC) o Composite Technology Corporation (CTC) o Twice the amount of electric power as conventional power lines. 32
  • 33. Brake rotors for high speed train Brake rotors for high speed train • particulate reinforced Aluminium alloy (AlSi7Mg+SiC particulates) • Weight of cast iron rotor is 120 kg/piece while MMC it is 76 kg/piece 33
  • 34. Cylinder liner Boxter engine block  Cylinder liner AlSi9Cu3 alloy with 25% Si.  Squeeze casting infiltration 34
  • 35. F-16 Fuel Access Door Covers • High specific strength and stiffness good bearing strength • Al Composites • 6092/SiC/17.5p • Wrought P/M material • Elimination of the skin cracking problem 35
  • 36. F-16 Ventral Fins • High specific stiffness and strength • Al-matrix composites • Rolled P/M • 6092/SiC/17.5p • Decreased deflections provide an increase in fin life 36
  • 37. Recreational products Skating shoe Base ball shafts Horse shoes Bicycle Frames 37
  • 38. Space Shuttle • Mid fuselage frames of Space Shuttle was made of MMCs 38
  • 39. Common MMCs and Applications 39
  • 40. Metal Matrix Automotive Brake Caliper Aluminum-matrix composite brake caliper using nanocrystallyne alumina fiber reinforcement. 40
  • 41. Application of advanced composite materials in Boeing 757-200 commercial aircraft. Source: Courtesy of Boeing Commercial Airplane Company. 41
  • 42. Boeing C-17 Globemaster III (large military transport aircraft) 42
  • 43. Cross-section of a composite sailboard. Source: K. Easterline, Tomorrow’s Materials (2nd ed.), p. 133. Institute of Metals, 1990. 43
  • 46. 46
  • 47. 47
  • 48. Disadvantages and Limitations of Composite Materials • Properties of many important composites are anisotropic - the properties differ depending on the direction in which they are measured – this may be an advantage or a disadvantage • Many of the polymer-based composites are subject to attack by chemicals or solvents, just as the polymers themselves are susceptible to attack • Composite materials are generally expensive • Manufacturing methods for shaping composite materials are often slow and costly 48